Bis[μ-1,3-bis(4,5-dihydroimidazol-2-yl)benzene-κ2 N:N′]bis[dichloridozinc(II)] N,N′-dimethylformamide disolvate
نویسندگان
چکیده
The title compound, [Zn(2)Cl(4)(C(12)H(14)N(4))(2)]·2C(3)H(7)NO, is located on a centre of inversion with one half of a complex mol-ecule and one dimethyl-formamide solvent mol-ecule in the asymmetric unit. The Zn(II) ion is tetra-hedrally coordinated by two organic ligands and two chloride ions. Each organic ligand acts as a bidentate ligand, connecting two Zn(II) ions, resulting in a dimeric [2:2] metallamacrocyclic structure. Adjacent mol-ecules are further linked by N-H⋯Cl hydrogen bonds and the solvent is linked to the complex by N-H⋯O hydrogen bonds.
منابع مشابه
Bis{μ-1,3-bis[(benzimidazol-1-yl)methyl]benzene-κ2 N 3:N 3′}bis[dichloridozinc(II)] dimethylformamide disolvate
In the title compound, [Zn(2)Cl(4)(C(22)H(18)N(4))(2)]·2C(3)H(7)NO, the 1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene ligand bridges two ZnCl(2) units, forming a centrosymmetric dinuclear mol-ecule. The Zn(II) atom shows a distorted tetra-hedral coordination within a Cl(2)N(2) donor set.
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